Chamfering the rear of a cylinder, (the mouths) can be tricky w/o the proper tools & stuff.
I shoot revolvers in USPSA competition, and it does aid in speed reloading. I prefer to allow someone with tons of experience AND the tools to do the work. There is a guy here in NC, goes by "DougGuy" on the cast boolit forum, that does the work, does it with a quick turnaround time, AND very reasonable. Especially if you don't want a ruined cylinder.
Now, as for doing the throats in a cylinder, I've done many, and have the proper tools for that. But Doug can also do those as well. He uses a hone instead of a reamer.